Firstly the setting for use appendable media (In your screenhot) is within a box called "Wenn dieser Auftrag startet"
what this means is if the job writes some data to one tape as an append and fills the remaining space on that first tape that the second tape is no longer using that setting because it is NOT the start of the job any longer (and in fact anything but the first tape used by any job has to be an overwrite operation when a new tape is needed)
There are some other things that could affect you as well:
- If the job in question is set to use a different media set than the one the tape belongs to - that will cause an overwrite request as you cannot put a single tape into 2 media sets and there is a requirement to overwrite if a tape changes media sets.
- if the job in question starts when an earlier job is still using the tape, then even when the earlier job finishes the second job may not be able to use that tape as a busy tape is also not appendable at that moment in time that the available media was first checked. Of course making sure the job is set to start well after the first job finishes (as well as using the same media set and setting the append option) would solve this.