Hello,
Do you wish to delete the Catalogs for any particular reason? Was it an upgrade from a previous version of Backup exec? You can go the Program Files\Veritas\Backup exec\NT\catalogs folder, rename it to catalogs.old and then restart all the BE services. This will be as good as deleting it. A nex catalog folder will be created.
Revert in case you still have questions on this.
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Regards.