Hello,
1. Refer this technote for confirmation:
Title : Backup Exec 10.0 for Windows Servers Frequently Asked Questions (FAQ
http://support.veritas.com/docs/274569
2. Backup exec 9.1 options and agents will not work with backup exec for 10.0. You will need to buy licences for all the remote agents and options.
The Backup exec 9.1 software components for all these on the other hand will work. But it is advised to reinstall remote agents to all remote servers to prevent issues.
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