Max size for backup file, 900GB???
There's no point for doing that, because of the performance reasons. You might try to change settings between 2 to 10Gb per backup-to-disk-file size, to find the best performance. If you don't want to do that, just change the max file size to 4GB which is default setting.
Think about it; You have one 900GB backup file. Backup Exec knows what data is in your backup file, as it's cataloged by Backup Exec server. But, when you do need to restore files from your backups, still Backup Exec knows that ok, your files can be found from your 900GB backup file. BUT, Backup Exec doesn't know the exact location of the files you want to restore from your 900GB backup file. So Backup Exec needs to scan the whole 900GB backup file to find your files to restore them.
If you would split your backups to for example 5GB files, Backup Exec knows still knows where to find your files, only that when you want to restore something, Backup Exec would only need to scan 5GB file (or files if restoring plenty amount of data) and that would be quite more easier than scanning 900GB file.
Concurrent jobs, that's how many backup jobs you can run same time to your Backup-to-disk-folder. If you have there 2 as in your picture, you can run 2 jobs at same time to your B2D folder. You should not run jobs same time more than you have physical disks on your Backup-to-disk-folder device.
So, if you have Buffalo Terastation and for example 4 physical disks in it, you shouldn't run more than 4 jobs at same time, because of the performance reasons.
Backup Exec uses GRT only with Exchange, Active Directory, Sharepoint and VM backups. Not for basic file backups.
If you want to protect all your media, including Full and Incremental for one month, you should set overwrite protection to one month. If you want that your backup files gets overwritten after a month, you should set your media overwrite protection for example to one day less than month, because the overwrite protection period starts when backup is written to backup-to-disk or tape media.
And if you use for example 2 to 10GB backup files, you don't need to worry about append period that much.