hi keith,
I think you are messed of something. Have a look if below advises helpe you.
When you label a tape, it is placed in the scratch Media set, and is thus available for any job.
When you move any tape into a media set, it immediately takes on all properties of the new media set (OPP and APP) as of the time it is moved. If the OPP is three weeks, it will be three weeks before it can be written to, even if you just labeled it 5 minutes ago.
Label your tapes and let BE move them from scratch into the media set defined for whatever job pulls them.
If you are worried that a weekly job will pull a daily tape, set up partitions and change your jobs to point to them rather that "All Pools" or the library itself.
See http://seer.support.veritas.com/docs/206843.htm
Harry