Once you setup your Exchange 2007 infrastructure you will need to move your mailboxes to the Exchange 2007 server. If you have the luxury of time to do the migration then the mailbox size is not much of a concern.
Here are the areas that may be of concern.
If you move the mailboxes when they have not been archived then your new 2007 stores will grow. If the items are already archived then the mailbox move will be fast and the stores will not have a large initial size.
I'm sure other admins may comment on other concerns.
If you do not care about the size of the store after a full migration and the time it takes to move the data in each mailbox then wait and install EV afterward.
Jim S.