Refer the following documents
http://support.veritas.com/docs/340834 Best practices for Backup Exec 2010 Deduplication Option
http://support.veritas.com/docs/347680When trying to make any changes to a DeDuplication folder the following error occurs "Invalid Physical Volume Library Robot Identifier"
http://support.veritas.com/docs/348035When a media server that has the Deduplication Option installed on it is promoted to a SSO (Shared Storage Option) Secondary server, Deduplication devices are removed from the Devices view in Backup Exec. In addition, the Deduplication services are stopped and set to manual.