I am not sure about replication exec but DFS/FRS will still replicate the whole database file if as it changes, not the changes to the file - so you'd be looking at replicating a 100GB file every time a change occured, or even if you set the replication schedule to out of hours, its still going to take 20 hours as before - not good.
Doubletake, for example, only replicates the bits and bytes that have actually changed within the file hence you don't consume much bandwidth over a WAN link.