Not sure about the error you're getting, but in regard to getting the catalog information, you will need to run an inventory and catalog on each tape separately. Backup Exec does not prompt you to insert the next tape in the set, I suppose because in some circumstances that would be a bad thing. After all, if you just wanted to restore one file, and new which tape it was on (since you've got the backup logs still), you wouldn't want to waste time running catalogs on all the other tapes which you know you don't need. Also, if one of the tapes was destroyed, would you want the entire set written off, or keep the option of restoring the data which remains on the other tapes if required.
Keith