Hello,
With backup exec 10.0, you can get 44 reports. Out of these, the 'Media set' report will suit your requirements.It lists all the media sets and media used by backup exec. The media statistics such as Soft and Hard read and write errors are also shown.
In order to know more on how to use this report effectively, refer to page 587 in the Reports chapter in the Backup exec Administrators manual for 10.0. You can download it at the following link:
http://support.veritas.com/docs/269777
Hope this answers your question. Revert in case of doubts.
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Regards.