That's why I said it sounds like the first job is not finishing before the second starts
1st job Overwrite - Grab a scratch volume and start writing.
2nd job Append - Look for an appendable volume in the target media set, then continue on that volume.
If the job fills the tape, grab a scratch and initialize, then finish the job
etc.
if you have multiple scratch volumes in a partition, they should be used in turn, subject to the preceeding