Backup Exec does not provide multi- tape streaming in one job.
I belive that NetBackup might be able to.
For Backup Exec to write two two tapes simultaneously you create 2 jobs with 2 different selection lists where both jobs target the library as a device. Then have the jobs scheduled to start in parallel. Note if you use a Policy and 2 selections lists it will automatically start them in parallel and maintain your GFS schedule.
If you don't use a single policy (but either use 2 polcieis or 2 jobs) , you can you can also parttion the slots in the library (from the Backup Exec devices section) so that you know that Job 1 only used the tapes from certain slots and job 2 uses tapes in different slots - although if you do this you target the partition not the library itself. But it does make it easier to knwo which tapes are liekly to have which data on them.