Answers to your question
1. The backup are written to the tape as per the options you select in the Job ie. Media set , overwrite or append etc
For eg If you have selected the option to overwrtie the tape in the backup job properties , Even if there is space in any of the tape ,backup job would look for the tape which can be overwritten . Similary when you select a media set in the backup job properties it would first see if there is any tape in that media set which can be overwritten or appended as per the option selected in the job ...
2. In the media properties section of a tape, the 'Used Capacity' value represent the amount of data written to tape regardless if compression was used or not. This was enhanced from v11d whereas in v10d the 'Used Capacity' value was the backup set size and not the amount of data written to the tape.
For example, if a 2GB data backup job was compressed (by hardware or software) to 1GB to a new tape, the 'Used Capacity' value for that tape would be 1GB. If the same backup was written to a new tape without enabling compression, then the 'Used Capacity' value would be 2GB.
Refer the following doc
http://support.veritas.com/docs/342158