You have 10 slots and want to do a full backup every day.
I'm going to assume you mean 'every day' Mon-Fri.
I'm also going to assume you have 10 tapes - enough for 2 weeks.
On the Exabyte media set you created, set the overwrite protection to 13 days
(or 6 days if you only have 5 tapes).
Now, load up and inventory the tapes.
On the 'Media' tab, move ALL of the tapes to 'Retired Media'
For today, move ONLY the tape you want backup to use to 'Scratch'
When backup runs, it will use that tape and put it in your Exabyte media set.
Next day, do the same - move ONLY the tape you want it to use to 'Scratch'.
You will repeat this process every day until you are once through your entire set of tapes.
After that, provided all backups process correctly, your tapes will be used in order.
If it helps you conceptually and visually, you can load them in the slots in order, but you don't really have to.
Cheers