Is it waiting for resources (tapes/drives)?
Anything in the logs?
Admin Guide:
"...
If problems occur with synthetic backups, the following debug logs are required to diagnose the problem:
■ On the master server: bpsynth, bpdbm, and the log files located in /usr/openv/logs as described in the NetBackup Troubleshooting Guide.
■ On the media server(s): bptm (if any tape images), bpdm (if any disk images), bpcd
..."
Unfortunately I never got to fully test synthetic backups as colleagues 'trashed' the client I was using whilst I was on leave! Therefore I can't comment directly on the niceties of running synthetic backups in the 'real-world'!