The solution described by Jon SHOULD work.
But the only way to absolutely guarantee that a job writes to a specific tape is to create partitions in your loader, then edit you jobs to point to the associated partition. 'Course this will mean the you need a job for each night of the week, but ...
See
http://seer.support.veritas.com/docs/262055.htm
http://seer.support.veritas.com/docs/206843.htm
http://seer.support.veritas.com/docs/241773.htm