Many thanks for that Gene, that's spot on. Looking at the netapp documentation on snapmirroring, it appears we'd incorrectly broken the relationship, leaving orphaned snapmirror entries. The following is how to resolve for anyone who gets into a similar state :)
Solution ID: kb6288
Title: How to delete a SnapMirror relationship - NetApp appliance
Problem Environment:
R200
Data ONTAP 6.5.2R1
SnapMirror
Problem Description
SnapMirror relationship still showing on "snapmirror" status output after breaking the relationship
How to delete a SnapMirror relationship
Solution:
To delete a SnapMirror relationship, follow the steps given below:
1. Break the snapmirror by issuing the command snapmirror break to the destination filer
2. Delete the entry on the /etc/snapmirror.conf in the destination filer, and
3. Do a snapmirror release on the source filer.
4.Then destroy the volume, re-create it and make the status restricted.
After this step, re-initialize the volume.This will clean the SnapMirror relationship.
Note: If the snapmirror status still shows broken-off relationship and snapshots that are no longer available, then delete the base snapshot on the destination SnapMirror. The command to find the base snapshot is: snapmirrror status -l .The output will show the base snapshot. Then delete the base snapshot by as shown: snap delete volume_name snapshot_name