I noticed the same issue that you are talking about. Everything that Puredisk is showing you is 10% more than Netbackup believes that it sees. The reason for this is that Puredisk by default will not allow the volume to go beyond 90% full, thus reserving 10% of the space to work with. I've been told that the reason for this is that Puredisk engines need free space to work with for routine maintenance tasks. If it runs out of space, you are at high risk of data corruption because it cannot properly process transaction logs and commit data.
That being said, Support did give me a workaround for this to allow me to grow to 95% utilization, however they STRONGLY advised that I not go beyond that due to risk of data corruption and inability to fix if it does not have the space needed to function. What I mean by this statement, is that you can make the same changes that I've done to get an extra 5% out of your Puredisk storage pool, but do not go beyond that or you will risk serious problems.
1) SSH over to your Puredisk node, locate 3 files under /Storage/etc/puredisk, agent.cfg, pdmbe.cfg, and contentrouter.cfg
2) Make a copy of these 3 files before you make any changes.
3) Open up agent.cfg with a text editor. Locate "softLimit", set to 90. Locate "HardLimit", set to 95
4) Open up contentrouter.cfg with a text editor. Set "LowSpaceThreshold" to 5%, and "VeryLowSpaceThreshold" to 3%
5) Open up pdmbe.cfg with a text editor. Set ""warningSpaceThreshold" to 5, and "veryLowSpaceThreshold" to 3
6) restart Puredisk services. Make sure to make this change on all Puredisk servers in the system.
7) Refresh the disk pool in Netbackup, you should now see 5% more space.