Note that the technote above (TN 245238) is for creating dual bootable rootdgs/bootdgs (ie: mirror the rootdisk, then detach and set up as separate bootable disk/environment) - which is useful but will not mirror the rootdisk as you originally requested.
To mirror the rootdisk with VxVM, you need to encapsulate the rootdisk if you haven't already done so (requires multiple reboots), then mirror the rootdisk onto rootmirror using with vxdiskadm (option 6 - MIrror Volumes on a Disk).
See details from VxVM Administrator's guide here for mirroring an encapsulated root disk:
http://sfdoccentral.symantec.com/sf/5.0/solaris/html/vxvm_admin/ag_ch_disks_vm28.html
Details to encapsulate the rootdisk (if not already done) here:
http://sfdoccentral.symantec.com/sf/5.0/solaris/html/vxvm_admin/ag_ch_disks_vm23.html
Once the rootdisk has been mirrored you should be able to boot from either rootdisk or rootmirror; the dual-boot described in the TN is more for scenarios such as patching/upgrade so you have a backup/can rollback to original state if needed (eg: you mirror the bootdisk, then detach the rootmirror, set up the alt boot environment, make changes to the original bootdisk; if something goes wrong and you need to back out, you should be able to boot off the alt/detach bootdg you set up earlier to get back to previous state)
hope that helps